Water (purification) – Science news

Using light, a prototype “green” material can purify enough daily drinking water for four people in just one hour. In tests, it killed nearly 100 percent of bacteria in 10 liters of water, researchers report February 7 in Chem.  Materials scientist Guoxiu Wang of the University of Technology Sydney and colleagues created ultrathin sheets of graphitic carbon nitride and added chemical groups like acids and ketones that lure electrons toward the sheets’ edges. There, the electrons jump onto oxygen atoms in water to form such microbe-dissolving oxygen chemicals as hydrogen peroxide.

drinking water

This new material, a 2-D sheet of graphitic carbon nitride, is a photocatalyst: It releases electrons when illuminated to create destructive oxygen-based chemicals that destroy microbes. The design avoids pitfalls of other similar technology. Today’s most effective photocatalysts contain metals that can leach into water as toxic pollutants. Others are non-metallic, like the new 2-D sheets, but are less efficient because they hold onto electrons more tightly.

The design killed 99.9999 percent of bacteria, including E. coli, in a 50-milliliter water sample. That’s as efficient as the best metal-based catalyst. And it killed microbes more quickly than previous best metal-free photocatalysts, which take over an hour to achieve what the new design did in 30 minutes.

The team then attached the nanosheets to the inside surface of plastic bags, purifying 10 liters of water in an hour.

“Our motive was to develop an efficient way to use sunlight to produce water for undeveloped or remote regions without a central supply of clean water,” Wang says, noting that the carbon and nitrogen composition should make the material inexpensive. The researchers next aim to work with engineers to scale up the design for commercial use.

https://www.sciencenews.org/article/water-purification-light-graphitic-carbon-nitride?utm_source=email&utm_medium=email&utm_campaign=latest-newsletter-v2&fbclid=IwAR3u7M5keFMQUGJJcdDDVkDaQD8Dy6kU3rBEbIUmR8oDZ6N1MlM8e9Y7wq0

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Solar water disinfection catalyzed by metal-free photocatalyst has emerged as a promising approach for clean water production. By using the edge-functionalized graphitic carbon nitride (g-C 34) as photocatalytic disinfectants, we find that the pathogen-rich water can be rapidly purified in 30 min with a disinfection efficiency of over 99.9999% under visible-light irradiation, which meets the requirement for drinking water.

The edge-functionalized g-C 34 shows a first-order disinfection rate that is five times higher than the previously reported best metal-free photocatalyst but only consumes 1/10 of the catalyst. The catalytic activity is also comparable to that of the best metal-based photocatalyst. Results of the highest occupied molecular orbitals and Mulliken charge distribution reveal that the exposed –COOH and C=O groups at the edges of g-C 34 nanosheets not only significantly promote charge separation but also induce the upward bending of the surface band, facilitating the generation of hydrogen peroxide.

https://www.cell.com/chem/fulltext/S2451-9294(18)30572-2

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